C-H bond amination by iron-imido/nitrene species

• 来源期刊: 科学通报(英文版)
• 学科: 化学
• 年，卷（期）: 2012,（19）
• 页码范围: 2352-2360
• 页数: 9页
• 分类号: O621.2
• 语种: 中文

摘要

C-H amination by iron-imido/nitrene species has attracted increasing research interest in recent years because of its potential use in economical and environmentally benign syntheses of amino compounds.With the aim of providing a comprehensive overview of this field,which is of interest to both the synthetic organic and inorganic communities,this paper reviews the status quo of C-H amination chemistry by iron-imido/nitrene intermediates,as well as by well-defined iron-imido/nitrene compounds,with special emphasis on their structure/reactivity correlations.Achievements,problems,and perspectives in this growing field are discussed.