Solvothermal Synthesis and Crystal Structure of a Zn（II） Microporous Metal-organic Framework

• 作者: CHEN Ping-Hua JIAO Xiao-Yan LI Dong-Ping LI Jing LI Xu LI Yong-Xiu
• 来源期刊: 结构化学
• 学科: 化学
• 关键词: 溶剂热合成 微孔金属 晶体结构 Zn X-射线衍射分析 骨架 配位聚合物 元素分析
• 年，卷（期）: 2012,（11）
• 页码范围: 1676-1680
• 页数: 5页
• 分类号: O614.121|TB383
• 语种: 英文

摘要

A novel three-dimensional Zn(II) coordination polymer, Zn3(C2H2N3)4(SiF6), has been synthesized under solvothermal conditions using 1H-1,2,4-triazole-3-carboxylic acid and zinc fluoride as the starting materials. The complex has been characterized by elemental analysis, IR, TG analysis and single-crystal X-ray diffraction analysis. The complex crystallizes in the tetragonal 14/mmm space group with a = 11.592(0), c = 7.526(1) A~, V= 1011.3(2)A3, Z = 2, M,. = 610.46, D, = 2.005 g/cm3 and F(000) = 596. The final R = 0.0312 and wR = 0.067 for 319 observed reflections with 1 〉 20(/). In the title complex, the Zn centers are interconnected by μ3-bridging triazole ligands to form a microporous three-dimensional metal-organic framework.

作者信息

序号	姓名	单位	发文数	被引次数	H指数	G指数
1	LI Dong-Ping		2	0	0.0	0.0
2	LI Jing		2	0	0.0	0.0
3	LI Xu		1	0	0.0	0.0
4	CHEN Ping-Hua		2	0	0.0	0.0
5	JIAO Xiao-Yan		2	0	0.0	0.0
6	LI Yong-Xiu		3	0	0.0	0.0