Synthesis, structures, and properties of two new binuclear complexes based on carboxyl-substituted nitronyl nitroxide: [M<sub>2</sub>(NITpBA)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>] (M = Zn and Cu)

• 作者: Jing Chen Jun-Jie Wang Kun-Tao Huang Qiang Huang You-Juan Zhang
• 来源期刊: 无机化学期刊(英文)
• 学科: 化学
• 关键词: Binuclear Complex Carboxyl-Substituted Nitronyl NITROXIDE Antiferromagnetic Exchange
• 年，卷（期）: 2013,（2）
• 页码范围: 35-41
• 页数: 7页
• 分类号: O6

摘要

Two new binuclear complexes, [M2(μ-NITpBA)4(H2O)2] (M = Zn 1 and Cu 2) [where NIpBA =?2-(4-carboxyl-phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide], were stylized and characterized. Magnetic susceptibility measurements revealed antiferromagnetic exchange interactions in two complexes.