Synthesis and characterization of a ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide

• 作者: Jing Chen Kun-Tao Huang Qiang Huang You-Juan Zhang
• 来源期刊: 无机化学期刊(英文)
• 学科: 化学
• 关键词: Nitronyl NITROXIDE ANIONIC Radical Ladder-Like STRUCTURE Cd (II) Complex
• 年，卷（期）: 2013,（3）
• 页码范围: 55-58
• 页数: 4页
• 分类号: O6

摘要

A ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide, [Cd2(NITpBA)4(H2O)4] (where NITpBA = 2-(4-carboxyphenyl)4,4,5,5-tetramethyl-4,5-dihydro-imidazol-1-oxyl-3-oxide), has been synthesized and characterized. X-ray analysis reveals that the compound 1 crystallizes in the monoclinic P21/c (No. 14) space group, and [Cd2(NITpBA)4(H2O)4] units are linked into infinite chains by radical bridging ligands.