This paper presents a development process of software with Graphic User Interface (GUI) for monitoring temperature in a Zigbee Wireless Network. The software framework design was introduced and analyzed in detail. In this paper, we wrote the software with C++ codes in Microsoft Foundation Class (MFC) programming of Visual C++ 6.0, which applied in wireless communication algorithms. Software test results show that temperature of Zibee network was real-time displayed by both text and curve, which achieved wireless temperature monitoring to Zigbee network.