Assessing the effect of land use change on ecosystem service value(ESV) can provide reference for sustainable land use and ecological environment protection. The land use information was extracted and analyzed based on Landsat TM images in Shuangliu County, Sichuan Province from 1992 to 2008, following remote sensing(RS) and GIS. The ESV of the land use change in study area was evaluated by adopting the service value method within Chinese terrestrial ecosystem. The results showed that:(1) the area of paddy field and forest land reduced in the 16 years, total area of construction land expanded fast on the basis of occupying paddy field and forest land.(2) The regional ESV increased by 4,508.859×104 RMB, but there is different change trend at different times, such as the ESV fell by 10.59% in 1992–2000, increased by 16.024% in 2000–2008.(3) The conversion from forest land and cultivated land to construction land caused a decline and negative flow in ESV, the total value was 2,197.233×104 RMB and 5,317.460×104 RMB.(4) All land use types showed that change of the ESV coefficient was less elastic, the relative sensitivity: forest land > cultivated land > water area. In terms of variability of ESV, water area change had greater influence on the change of ESV in the study area, and cultivated land and forest land had relatively smaller impact.