Dicyclopentamethylenethiuram Disulfide as Precursor of Mononuclear Complexes: Oxidative Cleavage of Metal-Metal Bond in [CpMo(CO)<sub>3</sub>]<sub>2</sub>and Molecular Structure of <i>cis</i>-[CpMo(CO)<sub>2</sub>{S<sub>2</sub>C-N(CH<sub>2</sub>)<sub>5</sub>}]

• 作者: Md. Manzurul Karim Md. RafikulIslam Mohammad R. Karim Shafikul Islam Tasneem A. Siddiquee
• 来源期刊: 晶体结构理论与应用(英文)
• 学科: 化学
• 关键词: Dicyclopentamethylenethiuram DISULFIDE (Dcpmtd) Oxidation NUMBER Oxida-tive Cleavage Coordination NUMBER Mononuclear Complex X-Ray Crystal Structure
• 年，卷（期）: 2017,（4）
• 页码范围: 67-72
• 页数: 6页
• 分类号: O6

摘要

The reaction of [CpMo(CO)3]2 with dicyclopentamethylenethiuram disulfide in refluxing xylene resulted a novel mono nuclear complex, cis-[(CpMo(CO)2{S2C-N(CH2)5}] as red crystals in moderate yield. The compound was formed by the oxidative cleavage of metal-metal bond in [CpMo(CO)3]2 together with a reductive sulfur-sulfur bond scission in the ligand.