The study area is a part of the Arabian Shield rocks of west central part of Saudi Arabia (150 km to the northeast of Jeddah). Geologically, the study area comprises five main geologic units i.e. 1) Layered basic volcanics and related volcaniclastics which are composed mainly from intercalated basalts and andesites and the related volcaniclastic derivatives, 2) Acidic volcanics and related volcaniclastics which are composed from layered and laminated dark and light acidic to intermediate igneous rocks, quartz and chert and marbles, 3) The Tertiary sedimentary succession which of volcaniclastic red beds and the intercalated clays;5) Tertiary volcanics of Harrart, and 4) The Quaternary wadi fill deposits which are composed from friable pebble supported conglomerates, sandstones and clays. Hydrogeologically, the groundwater aquifer of Wadi Qudaid is present mainly in two main horizons i.e. i) unconfined shallow aquifer (13 - 37 m) within the well porous and permeable conglomerates of the Quaternary Wadi deposits, ii) The deep confined aquifer of the bedded tuffaceous sandstones and mudstone of the Tertiary sedimentary succession of Ash Shumaysi Formation. The water samples are analyzed for major elements i.e. Ca, Mg, Na, Cl, SO4, HCO3 and the results show the normal content of these elements. The study related the addition and depletion of many elements during the running trip of the groundwater from the northeast (recharge area) to the southwest (downstream) area.