Fluoride-Responsive Organogel Based on Hydrazide Derivatives

• 作者: Chaoran Chen Guanghui Lv Hong Xin Lei Huang Lirong Lin Xinyang Chen
• 来源期刊: 材料科学与化学工程(英文)
• 学科: 化学
• 关键词: ORGANOGEL Hydrazine Derivatives Fluoride Response Hydrogen Bonding
• 年，卷（期）: 2020,（12）
• 页码范围: 8-17
• 页数: 10页
• 分类号: O62

摘要

<div style="text-align:justify;"> An organogelator named N-[3-(hydroxy)-4-(dodecyloxy)-benzoyl]-N’ (4’-nitro-benzoyl) hydrazide (D12) was synthesized. It could form stable gels in some of the tested organic solvent. SEM images revealed that the molecules self- assembled into fibrous aggregates in the xerogels. The X-ray diffraction analysis showed that the xerogel exhibited a layered structure. FT-IR studies confirmed that intermolecular hydrogen bonding between C=O and N-H groups was the major driving force for gelation of organic solvents. The gel exhibited gel-sol transition and color change upon addition of F<span style="font-size:10px;">^-</span>. An extended conjugated system formed through the phenyl group and a five-membered ring based on intramolecular hydro-gen bonding between the oxygen atom near the deprotonation nitrogen atom and the other NH, which is responsible for the dramatic color change upon addition of <span style="text-align:justify;white-space:normal;">F</span><span style="font-size:10px;text-align:justify;white-space:normal;">^-</span>. </div>