Through-space charge transfer blue polymers containing acridan donor and oxygen-bridged triphenylboron acceptor for highly efficient solution-processed organic light-emitting diodes

• 作者: Fan Chen Fosong Wang Jun Hu Lixiang Wang Shiyang Shao Xiabin Jing Xingdong Wang
• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2020,（8）
• 所属期刊栏目: ARTICLES
• 页码范围: 1112-1120
• 页数: 9页
• 语种: 英文

摘要

Three kinds of through-space charge transfer (TSCT) blue polymers containing non-conjugated polystyrene backbone together with spatially-separated acridan donor and oxygen-bridged triphenylboron acceptors having different substituents of tert-butyl,hydrogen and fluorine are designed and synthesized.The designed TSCT blue polymers possess photoluminescence quantum yields up to 70％ in solid-state film,single-triplet energy splitting below 0.1 eV,and typical thermally activated delayed fluorescence (TADF) effect.Meanwhile,the resulting polymers exhibit aggregation-induced emission (AIE) effect with emission intensity increased by up to ～27 folds from solution to aggregation state.By changing the substituent of acceptors to tune the charge transfer strength,blue emission with peaks from 444 to 480 nm can be realized for the resulting polymers.Solution-processed organic light-emitting diodes based on the polymers exhibit excellent device performance with Commission Intemationale de L'Eclairage (CIE) coordinates of (0.16,0.27),together with the maximum luminous efficiency of 30.7 cd A-1 and maximum external quantum efficiency of 15.0％,which is the best device efficiency for blue TADF polymers.

作者信息

序号	姓名	单位	发文数	被引次数	H指数	G指数
1	Fan Chen	中国科学院长春应用化学研究所	1	0	0.0	0.0
2	Jun Hu	中国科学院长春应用化学研究所	1	0	0.0	0.0
3	Xingdong Wang	中国科学院长春应用化学研究所	1	0	0.0	0.0
4	Shiyang Shao	中国科学院长春应用化学研究所	1	0	0.0	0.0
5	Lixiang Wang	中国科学院长春应用化学研究所	1	0	0.0	0.0
6	Xiabin Jing	中国科学院长春应用化学研究所	1	0	0.0	0.0
7	Fosong Wang	中国科学院长春应用化学研究所	1	0	0.0	0.0