To increase the angular bandwidth of volume holographic grating,we fabricate holographic gratings based on grating multiplexing technique by using thin films of photopolymers and polymer dispersed liquid crystals.Experimental re-sults confirm that the liquid crystal materials increase the refractive index modulation of the grating,enabling high dif-fraction efficiency with wide angular response compared to pure polymer materials.We observe that the fabricated holographic grating has near 80%of diffraction efficiency and about 18° of angular bandwidth,which can be further improved by modifying the liquid crystal/polymer mixtures and the grating multiplexing technique.The grating can be used to fabricate holographic waveguide structures for emerging applications in the near-eye display systems.