N-heterocyclic carbene-catalyzed radical reactions

• 作者: Kun-Quan Chen He Sheng Qiang Liu Pan-Lin Shao Xiang-Yu Chen
• 来源期刊: 中国科学：化学（英文版）
• 年，卷（期）: 2021,（1）
• 所属期刊栏目: MINI REVIEWS
• 页码范围: 7-16
• 页数: 10页
• 语种: 英文

摘要

While N-heterocyclic carbene(NHC)catalyzed electron-pair-transfer processes have been developed into an important tool for synthetically important bond formations during the past decades,the corresponding radical reactions via NHC catalysis have only received growing attention in the past six years.Taking into account the advantages NHC-catalyzed radical reactions might bring,such as creating new activation modes that were previously unobtainable,it is worthwhile to provide a conceptual understanding of this emerging area.Therefore,herein we give an overview of NHC-catalyzed radical reactions via different synthetic techniques.