Phosphorus-containing organic compounds are important feedstock for the synthesis of value-added bioactive mole-cules.Therefore,the development of highly efficient syn-thetic methods for the construction of phosphorus-element bonds has drawn huge attention in the past decades [1].Particularly,the formation of P-C bonds from phosphorus-centered radicals has been demonstrated to be one of the most efficient and convenient strategies,which has been widely applied for the synthesis of organic phosphorus compounds in recent years.