Achievement of promising cryogenic magnetocaloric performances in La1-xPrxFe12B6 compounds

• 作者: Zhipan Ma Xiaoshi Dong Zhenqian Zhang Lingwei Li
• 来源期刊: 材料科学技术（英文版）
• 年，卷（期）: 2021,（33）
• 页码范围: 138-142
• 页数: 5页
• 语种: 英文

摘要

The magnetic refrigeration(MR)utilizing magnetocaloric effect(MCE)has been recognized as an envi-ronmentally friendly and energy efficiency technology.Here we presented the magnetic properties and MCE in Pr-doped La1-xPrxFe12B6(x=0.05-0.2)itinerant-electron metamagnetic(IEM)compounds.A small amount of Pr doping La site can greatly improve the peak values in the magnetic entropy change ΔSM(T)curves,especially under relatively low magnetic field changes(ΔH).Additionally,the peak temperature increases gradually and the magnetic hysteresis reduces gradually with increasing x.The observed MCE in present La1-xPrxFe12B6 compounds is related to its field-induced first-ordered IEM transition.The peak values of ΔSM for La1-xPrxFe12B6 compounds reach 13.4,15.4,12.5 and 13.0 J/(kg K)at Tc～58,68,72 and 89 K for x=0.05,0.10,0.15 and 0.2 under ΔH of 0-7 T,respectively.The corresponding relative cool-ing power values are 462.3,480.7,372.4 and 375.7 J/kg.The present La1-xPrxFe12B6 compounds could be good candidates for active MR application if the magnetic and thermal hysteresis can be further reduced.The present work indicates that the LaFe12B6-based material system could also exhibit promising magne-tocaloric performances.