Synthesis and Crystal Structure of a Copper(Ⅱ)Complex with Funnel-like Ligand Based on Calix[6]arene

• 作者: WANG Yi-Feng SHU Mou-Hai
• 来源期刊: 结构化学
• 年，卷（期）: 2022,（3）
• 页码范围: 186-192
• 页数: 7页
• 语种: 英文
• DOI: 10.14102/j.cnki.0254-5861.2011-3312

摘要

The preparation method of a funnel like ligand derived from calix[6]arene and tris(2-pyridyl-methyl)anime has been improved.The Cu(Ⅱ)complex was obtained and characterized by ESI-MS,EPR,UV-Vis spectra and crystallographic analysis.In the complex,a guest acetonitrile molecule is introduced into the cavity of the ligand host via the coordination with Cu(Ⅱ)center.