KINETICS OF VINYL CHLORIDE (CO)POLYMERIZATION AT HIGH CONVERSION

• 来源期刊: 高分子科学(英文版)
• 年，卷（期）: 1999,（1）
• 页码范围: 13-19
• 页数: 7页
• 语种: 英文

摘要

This paper provides a summarized review on the kinetics of vinyl chloride homopolymerization in the absence and presence of chain transfer agents, of VC/DAP(diallyl phthalate) copolymerization with chain extension and/or slightly crosslinking functions, and of vinylidene chloride/VC random copolymerization.Models of rate, degree of polymerization or molecular weight, copolymer composition, gel fraction and crosslinking density were proposed and interpreted mechanistically.