Isostructural Transition of MgB2 Under High Pressure
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摘要:
The high-pressure behaviour of the superconductor MgB2 with a hexagonal structure has been investigated by
the in situ synchrotron radiation x-ray diffraction method under pressures up to 42.2 GPa in a diamond anvil
cell. An abrupt decrease of about 7% in the unit cell volume of this material occurs in the pressure range of
26.3-30.2 GPa. A split of the Raman spectrum was also observed. The jump of the compression curve and
Raman spectrum are ascribed to an isostructural transition in MgB2 at a pressure of 30.2 GPa.