A Convenient Synthesis and Molecular Structure ofRu(CO)3[Ph2PN(i-Bu)PPh2-P, P]

• 来源期刊: 中国化学(英文版)
• 学科: 化学
• 年，卷（期）: 2001,（5）
• 所属期刊栏目: Notes
• 页码范围: 528-529
• 页数: 2页
• 分类号: O6
• 语种: 英文

摘要

Ru(CO)3[Ph2PN(i-Bu)PPh2-P, P] was conveniently obtained by the reaction of Ru(DMSO)4Cl2 with Ph2PN(i-Bu)PPh2 and CO in the presence of Zn powder under mikl conditions. The crystal and molecular structure was determined by X-ray diffraction. This compound possesses a distorted trigonal bipyramidal configuration.