In this paper the least-squares mixed finite element is considered for solving secondorder elliptic problems in two dimensional domains. The primary solution u and the flux σ are approximated using finite element spaces consisting of piecewise polynomials of degree k and r respectively. Based on interpolation operators and an auxiliary projection,superconvergent Hi-error estimates of both the primary solution approximation uh and the flux approximation σh are obtained under the standard quasi-uniform assumption on finite element partition. The superconvergence indicates an accuracy of O(hr+2) for the least-squares mixed finite element approximation if Raviart-Thomas or Brezzi-DouglasFortin-Marini elements of order r are employed with optimal error estimate of O(hr+1).