Asymmetric Hydroformylation of Olefins Catalyzed by a Chiral Diphosphite-Rhodium Complex

• 来源期刊: 中国化学（英文版）
• 学科: 化学
• 年，卷（期）: 2004,（2）
• 页码范围: 203-206
• 页数: 4页
• 分类号: O6
• 语种: 英文

摘要

A C2-symmetrical aryl diphosphite derived from chiral binaphthol was prepared and its rhodium complex was used as catalysts in the asymmetric hydroformylation of olefins. High catalytic activity and good regioselectivity were observed. Up to 31.2% ee and 38.1% ee were achieved for the hydroformylation of 4-fluoro-styrene and vinyl acetate respectively. The influences of ligand-to-metal ratio, reaction temperature and the pressure of syn-gas on the enantioselectivity and regioselectivity were also studied.