Structure and Photoluminescence of Nano-ZnO Films Grown on a Si (100) Substrate by Oxygen- and Argon-Plasma-Assisted Thermal Evaporation of Metallic Zn
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摘要:
Nano-ZnO thin films were prepared by oxygen- and argon-plasma-assisted thermal evaporation of metallic Zn at low temperature, followed by low-temperature annealing at 300 ℃ to 500 ℃ in oxygen ambient.X-ray diffraction patterns indicate that the nano-ZnO films have a polycrystalline hexagonal wurtzite structure.Raman scattering spectra demonstrate the existence of interface layers between Zn and ZnO.Upon annealing at 400 ℃ for 1 h, the interface mode disappears, and photoluminescence spectra show a very strong ultraviolet emission peak around 381 nm.The temperature-dependent PL spectra indicate that the UV band is due to free-exciton emission.
Structure and Photoluminescence of Nano-ZnO Films Grown on a Si (100) Substrate by Oxygen- and Argon-Plasma-Assisted Thermal Evaporation of Metallic Zn