Synthesis and structures of new helical,nanoscale ferrocenylphenyl amides

• 来源期刊: 中国高等学校学术文摘·化学
• 关键词: ferrocenylphenyl synthesis crystal structure hydrogen bond amide
• 年，卷（期）: 2007,（1）
• 页码范围: 41-44
• 页数: 4页
• 语种: 英文

摘要

Two novel ferrocenylphenyl-containing amides have been synthesized by reaction of ferrocenylbencarboxylchloride and 1,2-di-(o-aminophenoxy)ethane.A single crystal X-ray analysis shows that compound 3 crystallizes in the triclinic system,space group P-1,and compound 4 crystallizes in orthorhombic system,space group Pca21.There areintramolecular H-bonds in both the compounds,two H-bonds in compound 3 and one in compound 4.The dihedral angels of Cp-ring and phenyl ring range from 3.8° to 20.8°.