PM567-Doped solid dye lasers based on PMMA

• 来源期刊: 中国物理B（英文版）
• 关键词: solid dye laser PMMA slope efficiency photostability
• 年，卷（期）: 2007,（12）
• 页码范围: 3681-3684
• 页数: 4页
• 语种: 英文

摘要

Polymers are a kind of attractive hosts for laser dyes due to their high transparency in both pumping and lasing ranges and superior optical homogeneity. In this paper solid dye samples based on polymethyl methacrylate (PMMA)doped with different concentrations of 1, 3, 5, 7, 8 -pentamethyl-2, 6-diethylpyrromethene-BF2 (PM567) are prepaed.The absorption, fluorescence and lasing spectra of the samples are obtained. Wide absorption and fluorescence bands are obtained and a red shift of the maxima of the lasing emission spectra is observed. With the second-harmonic generation of Q-switched Nd:YAG laser (532 nm, ～20 ns) pumping the samples longitudinally, the slope efficiencies of the samples are obtained. There is an optimal dye concentration for the highest slope efficiency when the pumping energy is lower than some typical value (～250 m J), and the highest slope efficiency 35.6% is obtained in the sample with a dye concentration of 2 × 10-4 mol/L. Pumping the samples at a rate of 10Hz with a pulse energy as high as 200 mJ (the fluence is 0.2J/cm2), the output energy drops to one-half of its initial value after approximate 15500 pulses and the normalized photostability is 5.17GJ/mol. A kind of solid dye laser which could have some applications is built.