Synthesis and high temperature thermoelectric transport properties of Si-based type-I clathrates

• 来源期刊: 中国物理B（英文版）
• 关键词: type-I clathrate thermoelectric materials synthesis
• 年，卷（期）: 2009,（7）
• 页码范围: 3084-3089
• 页数: 6页
• 语种: 英文

摘要

N-type Si-based type-I clathrates with different Ga content were synthesized by combining the solid-state reaction method,melting method and spark plasma sintering(SPS)method.The effects of Ga composition on high temperature thermoelectric transport properties were investigated.The results show that at room temperature,the carrier concentration decreases,while the carrier mobility increases slightly with increasing Ga content.The Seebeck coefficient increases with increasing Ga content.Among all the samples,Ba7.93Ga17.13Si28.72exhibits higher Seebeck coefficient than the others and reaches -135 μV·K-1 at 1000 K.The sample prepared by this method exhibits very high electrical conductivity,and reaches 1.95×105 S·m-1 for Ba8.01Ga16.61Si28.93 at room temperature.The thermal conductivity of all samples is almost temperature independent in the temperature range of 300-1000 K,indicating the behaviour of a typical metal.The maximum ZT value of 0.75 is obtained at 1000 K for the compound Ba7.93Ga17.13Si28.72.