Intrinsic oxidation kinetics of sulfite catalyzed by peracetic acid under different water quality and light conditions

• 来源期刊: 中国科学B辑(英文版)
• 年，卷（期）: 2009,（1）
• 页码范围: 109-116
• 页数: 8页
• 语种: 英文
• DOI: 10.1007/s11426-008-0154-9

摘要

Oxidation of sulfite is an important process in wet flue gas desulfurization. Using highly purified water or distilled water as a reaction medium and a transparent or an opaque intermittent reaction apparatus, the intrinsic oxidation kinetics of sulfite catalyzed by peracetic acid was investigated under four dif-ferent conditions. The reaction order of the reagents and the activation energy were obtained. The re-sults indicate that water quality and light have no obvious effects on the reaction order and activation energy, but have an influence on the reaction rate constant. The mechanism of the intrinsic reaction is proposed. The results derived with this mechanism are in good agreement with the experimental re-sults.