V2O5/C catalyst for liquid phase oxidation of glyoxal to glyoxylic acid

• 来源期刊: 中国科学B辑(英文版)
• 年，卷（期）: 2009,（7）
• 页码范围: 1057-1062
• 页数: 6页
• 语种: 英文
• DOI: 10.1007/s11426-009-0145-5

摘要

study of the catalytic activity of V2O5/C catalyst for the oxygen oxidation of glyoxal has been made,showing that glyoxylic acid can be formed without control of pH value and there is little oxalic acid from the excessive oxidation of glyoxylic acid.The studies of XRD and TEM have shown that V2O5 diffraction peaks gradually strengthen with the increase of the content of V2O5.With the content of 3% V2O5 and the calcination temperature of 573 K,V2O5/C catalyst displayed the best activity and selectivity.The conversion of glyoxal and the selectivity of glyoxylic acid reached 18.76% and 77.70% after 5 h,respectively.Moreover,V2O5/C catalyst showed small deactivation after recycling three times,which indicates that V2O5/C has a higher stability than noble metal catalysts in the reaction medium.