High-frequency samples have been collected at Jiangjia Spring, the outlet of Qingmuguan underground river system (QURS) in Chongqing in late April, 2008. The variations of hydrogeochemical compositions are found responding rapidly to storm events. Principal component analysis (PCA) of the 20 variables is employed to interpret the relationships with specific processes that control the groundwater hydrogeochemical formations. Through PCA, 84.961%of the total amount information is extracted to indicate the fo...