The Synthesis of Arylsulfonylphthalimides and Their Reactions with Several Amines in Acetonitrile

• 作者: Halil Kutuk Seyhan Ozturk
• 来源期刊: 有机化学国际期刊(英文)
• 学科: 化学
• 关键词: Arylsulfonyl PHTHALIMIDES Mechanism SUBSTITUENT Effect Activation Entropy
• 年，卷（期）: 2011,（4）
• 页码范围: 202-206
• 页数: 5页
• 分类号: O6

摘要

In this study, several N-(p-substituted-arylsulfonyl)phthalimides (1a-e) were synthesized. The synthesized compounds were then examined with respect to their substitution reactions with t-butylamine, diethylamine, cyclohexylamine, and trans-1,2-diaminocyclohexane in acetonitrile. In order to determine the mechanism, substituent effect, activation entropy, and nucleophile effect were used as criteria.