Electrical, Structural and Interfacial Characterization of HfO2 Films on Si Substrates
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摘要:
Hafnium oxide films are deposited on Si(100) substrates by means of rf magnetron sputtering.The interfacial structure is studied using high-resolution transmission electron microscopy(HRTEM) and x-ray photoelectron spectroscopy(XPS), and the electrical properties of the Au/ HfO2/Si stack are analyzed by frequency-dependent capacitance-voltage(C-V-f) measurements.The amorphous interfacial layer between HfO2 and the Si substrate is observed by the HRTEM method.From the results of XPS, the interfacial layer comprises hafnium silicate and silicon oxide.For C-V-f measurements, the C-V plots show a peak at a low frequency and the change in frequency has effects on the intensity of the peak.As expected, rapid thermal annealing can passivate the interface states of the HfO2/Si stack.