A high-power all-fiber single-frequency polarization-maintained (PM) laser operating at 1083 nm is demonstrated using a master oscillator power amplifier (MOPA) structure.The seed source of this MOPA laser system is an in-house-built ring-cavity fiber oscillator.Four-stage amplification configuration is employed,in which the maximal output power of the main amplifier is 90.4 W,corresponding to a conversion efficiency of 72.5%.The polarization extinction ratio of the output light is 13 dB.The amplified spontaneous emission is suppressed by a factor of over 25 dB,and no stimulated Brillouin scattering effect is observed when a large-mode-area and high absorption coefficient PM gain fiber is employed.