Iron-catalyzed benzylation of 1,3-dicarbonyl compounds by simple toluene derivatives

• 来源期刊: 科学通报(英文版)
• 学科: 化学
• 年，卷（期）: 2012,（19）
• 页码范围: 2382-2386
• 页数: 5页
• 分类号: O643.32
• 语种: 中文

摘要

An iron-catalyzed oxidative C-C bond formation by the reactions of simple toluene derivatives with 1,3-dicarbonyl compounds is developed.A benzylic radical addition to a benzoylmethanato iron species is proposed for the transformation.