Structural, Magnetic and Dielectric Properties of Fe-Co Co-Doped Ba<sub>0.9</sub>Sr<sub>0.1</sub>TiO<sub>3</sub>Prepared by Sol Gel Technique

• 作者: Emad Girgis Fawzi Gooda El Desouky Hesham Azmi El Meleegi Ibrahim Sayed Ahmed Farag Inas Kamal Batttisha Mohamed Ali Ahmed Mostafa Kamal
• 来源期刊: 玻璃与陶瓷期刊(英文)
• 学科: 化学
• 关键词: Sol Gel NANO-STRUCTURE MAGNETIC Hysteresis Loop DIELECTRIC Permittivity NANO-COMPOSITE BaSrTiO3 (BST) TEM XRD SEM
• 年，卷（期）: 2014,（2）
• 页码范围: 19-28
• 页数: 10页
• 分类号: O6

摘要

The structural, dielectric and magnetic properties of pure and Fe-Co co-doped Ba0.9Sr0.1TiO3, (Ba(1-x)SrxTiO3, where (x = 0.10) and (Ba0.9Sr0.1Ti(1-x-y)FexCoyO3), where (x = 0.1, y = 0) and (x = 0 and y = 0.10) and (x = 0.5, y = 0.5) in powder form, abbreviated as (BST) and (BST10FO), (BST10CO) and (BST5F5CO), respectively were prepared by a modified sol gel technique. Crystallization, surface morphology and electrical behavior of BST are improved by Fe3+ and Co2+ ions with optimized grain size. Phase identification by using X-ray diffraction and surface morphology will be studied by using transmission electron microscope (TEM) and scanning electron microscope imaging (SEM). Phase identification by using X-ray diffraction and surface morphology evaluation by using transmission electron microscope (TEM) and scanning electron microscope imaging (SEM) will be studied. The nano-scale presence and the formation of the tetragonal perovskite phase as well as the crystallinity were detected using the mentioned techniques. The dielectric properties of the prepared samples have been investigated as a function of temperature and frequency. The dielectric measurements are carried out in the frequency range of 42 Hz - 1 MHz, at temperature ranging between 25°C and 250°C. The results showed an abrupt decrease in the dielectric permittivity by increasing the frequency range. The magnetic hysteresis loop confirmed enhancement in the magnetization properties by co-doping with Fe3+-Co2+ ions. An increase in the saturation of the magnetization at room temperature was detected by decreasing the crystallite sizes of the prepared samples.