Microstructure-Property Relationship in Self-Crosslinked Non-Derivative Acetic Acid Lignin-Containing Polyurethane Membranes

• 作者: Baojian Liu Haihua Wang Zhongjin Li
• 来源期刊: 绿色与可持续化学(英文)
• 学科: 化学
• 关键词: POLYURETHANE Phase Behavior Acetic ACID LIGNIN MEMBRANE Microstructure
• 年，卷（期）: 2014,（3）
• 页码范围: 162-174
• 页数: 13页
• 分类号: O6

摘要

With the assistance of different solvents, self-crosslinked acetic acid lignin-containing polyurethane (LPU) membranes were synthesized. Compared with tetrahydrofuran and dioxane, N, N-dimethylacetamide with stronger polarity together with higher boiling point was demonstrated to be beneficial for preparing LPU particles of smaller size and enhanced binding force. It was also found that lignin domain can interpenetrate into polyurethane domain well with 43.3% lignin addition, resulting in enhanced phase mixing and better performance. In addition, relative homogeneous and smooth LPU membrane can be obtained with 2% TMP addition, while stress crack took place when TMP content was greater than 3%.