Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay
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摘要:
With the support by the National Natural Science Foundation of China and the Chinese Academy of Sciences,the research team led by Prof.Liu Guosheng (刘国生) at Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,and Prof.Shannon Stahl at the University of Wisconsin-Madison,discovered a copper-catalyzed radical relay pathway for enantioselective conversion of benzylic C-H bonds into benzylic nitriles,which was published in Science (2016,353(6303):1014-1018).