Quality Assessment Statistic Evaluation of X-Ray Fluorescence via NIST and IAEA Standard Reference Materials

• 作者: A. M. Mustafa A. M. Salih E. M. A. Mohamed Farouk I. Habbani Ftihia Seedig O. M. H. Ahmed
• 来源期刊: 核科学与技术国际期刊(英文)
• 学科: 医学
• 关键词: XRF QC REFERENCE MATERIAL Statistic EVALUATION
• 年，卷（期）: 2017,（2）
• 页码范围: 121-128
• 页数: 8页
• 分类号: R73

摘要

The aim of this study is a quality assessment of X-ray fluorescence laboratory located at the University of Khartoum. The X-ray fluorescence spectrometer system consists, a set of three 109Cd sources of an initial nominal activity of 10 μCi, and Si(Li) detector Energy Dispersive XRF(EDXRF) systems. It is important to carry out this work because it has an effective contribution for a wide range of research and services. The assessment was carried out by measuring 8 NIST-2709a (soil) and 13 IAEA-155 (milk powder) standard reference material samples for repeatability examinations to test the measurement precision. The total combined standards uncertainty values for XRF lab were estimated by an error from repeatability measurements adding 2.6% for error propagation related to the method. For accuracy assessment, three standard statistic approaches were applied, i.e. the Bias %, zeta-score, and En-number. The bias of all elements for both standard materials was found to be within a deviation range from −28% to 7.8%. The results of all elements for both the zeta-score test and En-number have satisfactory results except Th (Thorium) and Zr (Zirconium) which consider as questionable results for NIST SRM 2709a and unsatisfactory results for En-number.