Ruthenium-promoted reductive transformation of CO2

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2017,（7）
• 页码范围: 841-852
• 页数: 12页
• 语种: 英文
• DOI: 10.1007/s11426-016-0473-5

摘要

The reductive transformation of CO2 to energy related products including formic acid,CO,formamide,methanol and methylamine could be a promising option to supply renewable energy.In this aspect,ruthenium has found wide application in hydrogenation of various carbonyl groups,and has successfully been applied to reductive transformation of CO2 with high catalytic efficiency and excellent selectivity.In addition,ruthenium complexes have also served as effective photosensitizers for CO2 photoreduction.Classified by reductive products,this review summarizes and updates advances in the Ru-catalyzed reduction of CO2 along with catalyst development on the basis of mechanistic understanding at a molecular level.