Direct and highly selective conversion of CO2 into gasoline fuels over a bifunctional catalyst
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摘要:
CO2 is an economical,nontoxic,renewable and abundant carbon source.The chemical utilization of CO2 into value-added products is very attractive because it can not only alleviate the global warming caused by increasing atmospheric CO2 concentration,but also offer a solution to replace dwindling fossil fuels [1].Thus,much attention has been paid to the CO2 conversion to various C1 feedstock (e.g.,CH4,CH3OH,CO,HCOOH).However,due to the extreme inertness of CO2 and a high C-C coupling barrier,it is still a great challenge to synthesize C2+products (products with more than two carbons) directly from CO2,such as gasoline (C5-C11 hydrocarbons),which is a very important transportation fuel widely used around the world.If CO2 can be directly and efficiently converted into gasoline fuels,the dream toward "cycling carbon by mimicking nature" will come true.