Recyclable bifunctional aluminum salen catalyst for CO2 fixation: the efficient formation of five-membered heterocyclic compounds

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2017,（7）
• 页码范围: 979-989
• 页数: 11页
• 语种: 英文
• DOI: 10.1007/s11426-016-0405-3

摘要

A variety of unique Al(salen) complexes functionalized by imidazolium-based ionic liquid (IL) moieties with the salen ligand at the two sides of 3,3'-position have been successfully prepared,rather than familiar 5,5'-position reported previously.The catalytic activity obtained by these bifunctional catalysts could be superior to those of the binary type catalysts in the formation of five-membered heterocyclic compounds from the cycloaddition reaction of CO2 and three-membered heterocyclic compounds (including terminal epoxides and N-substituted aziridines),presumably due to the distinguished intramolecularly synergistic catalysis,which might lead to perform the cycloaddition reaction at ambient conditions and retain excellent yield and unprecedented chemo-or regioselectivity.Moreover,the polyether-based trifunctional Al(salen) catalysts with the best catalytic performance could be regenerated and reused at least eight times without any obvious decreases in catalytic activity.Finally,the kinetic investigation suggested the structure of catalysts had important influences on the catalytic activity,thereby proposing the possible reaction mechanism.