The glyco-regioisomerism effect on dynamic interactions between glycopolymers with galactose pendants and benzoxaborole-containing polymer

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2018,（1）
• 页码范围: 71-75
• 页数: 5页
• 语种: 英文
• DOI: 10.1007/s11426-017-9130-5

摘要

This work investigated the effect of glyco-regioisomerism of glycopolymers on their dynamic interaction with benzoxaborole-containing polymers.Two kinds of glycopolymers,P-1-Gal and P-6-Gal,i.e.galactoside pendant group linked to the identical main chain through its anomeric (Cl) and C6-hydroxyl group position,respectively,were studied.We found that P-6-Gal showed stronger binding strength to the PNIPAM-co-PBOB polymer than P-1-Gal did,which controlled the macroscopic property of the resultant hydrogels at a molecular level.