POSS-embedded supramolecular hyperbranched polymers constructed from a 1→7 branching monomer with controllable morphology transitions

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2018,（3）
• 页码范围: 311-318
• 页数: 8页
• 语种: 英文

摘要

The research on the supramolecular hyperbranched polymers (SHPs) that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications.Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers (POSS-SHPs) with varied morphology and size by controlling monomer concentration and mixed solvents.The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.