CO Catalytic Oxidation of Pt-Loaded Perovskite BaTiO3 Near Ferroelectric-Phase Transition Temperature

• 来源期刊: 金属学报（英文版）
• 年，卷（期）: 2018,（10）
• 页码范围: 1031-1037
• 页数: 7页
• 语种: 英文

摘要

Perovskite BaTiO3 (BTO) nanocrystals with a size of 150-200 nm have successfully been synthesized via a facile hydrothermal method by employing titanate nanowires as synthetic precursor.Tetragonality and spontaneous ferroelectric polarization of BTO nanocrystals have been determined by X-ray diffraction and transmission electron microscopy investigations.BTO nanocrystals loaded with Pt nanoparticles in a size of 2-5 nm have been explored as a catalyst towards CO oxidation to CO2.It is interesting to find that CO catalytic conversion rate over Pt-BTO nanocrystals gradually decreased and further increased near 100 ℃ when the catalytic temperature keeps increasing,whereas the conversion behavior in oxides is expected to be enhanced upon the catalytic temperature grows.Using differential scanning calorimetry and first-principle calculations,the observed catalytic behavior has been discussed on the basis of the ferroelectric polarization effect and the ferroelectric-paraelectric transition of BTO nanocrystals with a Curie temperature of ～ 110 ℃.Below Curie temperature,CO catalytic oxidation could be significantly tailored by ferroelectric polarization of BTO nanocrystals via a promoted dissociation of 02 molecules.The findings suggest that a ferroelectric polarization in perovskite oxides could be an alternative way to modify the CO catalytic oxidation.