Oxidant-free dehydrogenative coupling via electrooxidation: a mild, green,and sustainable route to synthesize aryl amines integrated with hydrogen evolution

• 来源期刊: 科学通报（英文版）
• 年，卷（期）: 2018,（11）
• 页码范围: 666-668
• 页数: 3页
• 语种: 英文

摘要

Transition-metal (TM)-catalyzed coupling reactions play a fundamental and powerful role in synthetic chemistry,which have been widely applied in both academia and industry [1].However,the classic coupling reactions usually using organic halides as partners,suffering from the pre-functionalization of the substrates and dealing with stoichiometric amounts of salts byproducts,which add the complexity of operation and reduce the overall efficiency of the transformation [2,3].Therefore,developing efficient,highly atom-economical,and environmentally benign synthetic methods are highly desirable from a sustainable point of view.