8.0％ Efficient all-polymer solar cells based on novel starburst polymer acceptors

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2018,（5）
• 页码范围: 576-583
• 页数: 8页
• 语种: 英文

摘要

The polymer N2200,with its π-conjugated backbone composed of altemating naphthalene diimide (NDI) and bithiophene (DT)units,has been widely used as an acceptor for all-polymer solar cells (all-PSCs) owing to its high electron mobility and suitable ionization potential and electron affinity.Here,we developed two naphthalene diimide derivatives by modifying the molecular geometry of N2200 through the incorporation ofa truxene unit as the core and NDI-DT as the branches.These starburst polymers exhibited absorption spectra and molecular orbital energy levels that were comparable to N2200.These copolymers were paired with the wide-bandgap polymer donor PTzBI-O to fabricate all-polymer solar cells (all-PSCs),which displayed impressive power conversion efficiencies up to 8.00％.The improved photovoltaic performances of all-PSCs based on these newly developed starburst acceptors can be ascribed to the combination of increased charge carrier mobilities,reduced bimolecular recombination,and formation of more favorable film morphology.These fmdings demonstrate that the construction of starburst polymer acceptors is a feasible strategy for the fabrication of high-performance all-PSCs.