Towards understanding the correlation between UO22+ extraction and substitute groups in 2,9-diamide-1,10-phenanthroline

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2018,（10）
• 页码范围: 1285-1292
• 页数: 8页
• 语种: 英文

摘要

2,9-Diamide-1,10-phenanthroline (DAPhen) ligands represent a new family of tetradentate extractants given their strong affinity to actinides and the CHON principle.Among this family,N,N'-diethyl-N,N'-ditolyl-2,9-diamide-l,10-phenanthroline (Et-Tol-DAPhen),initially reported by us,exhibits excellent selectivity towards actinides (U,Th,Am,Pu) over lanthanides and thus can be potentially applied in the group actinide extraction (GANEX) process for the group separation of actinides.In this article,by tailoring the lengths of alkyl chains,we synthesized other four DAPhen ligands with different substitute groups in the diamide moieties,and characterized the relationship between properties and substitute groups of DAPhen ligand.The extraction results show that three of the ligands exhibit high performance in UO22+ extraction from an acidic solution and the extracted UO22+ can be easily stripped by only using ultrapure water.Spectrophotometry titration confirms that UO22+ combined with all the four ligands in 1:1 mode.The extended X-ray absorption finestructure (EXAFS) study shows that six donor atoms comprise the first equatorial shell of the UO22+ ions bonded by the DAPhen ligands,among which two nitrogen and two oxygen atoms are from the DAPhen ligand,while other two oxygen atoms are from one nitrate ions.This article promises to provide basic data for assessing the feasibility of this kind of DAPhen ligands applied in actinides separation from nuclear wastes.