A coordination compound featuring a supramolecular hydrogen-bonding network for proton conduction
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摘要:
A new coordination compound [Mg(L)(H2O)5·H2O] (NKU-109,H2L=5-(4H-1,2,4-triazol-4-yl)benzene-1,3-dicarboxylic acid) was solvothermally synthesized,featuring a supramolecular hydrogen-bonding network.A good proton conductivity of 5.87 × 10-4 S/cm was recorded at 70 ℃ and a relative humidity of 75% in alternating current (AC) impedance experiment,which sheds a new light on the design of proton conduction materials based on coordination compounds.