Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes

• 来源期刊: 高等学校化学研究（英文版）
• 年，卷（期）: 2019,（2）
• 页码范围: 229-234
• 页数: 6页
• 语种: 英文
• DOI: 10.1007/s40242-019-8279-2

摘要

By utilizing terpyridine-bridged parallel metallo-complexes as dication metallo-bisviologens,herein we present the synthesis and characterization of two novel supramolecular complexes.1-Methylpyridin-1-iumterpyridine ligands and their metallo-complexes were first designed and synthesized,and the association of methylpyridiniums with dibenzo-24-crown-8 ether(DB24C8) afforded the desired novel complexes through host-guest interactions.The self-assembly behavior of the supramolecular complexes was comprehensively investigated and could be exploited for further construction of 1D to 3D supramolecular infrastructures.