Triphenylphosphine and sodium iodide: a new catalyst combination to rival precious metal complexes in visible light photoredox catalysis

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2019,（9）
• 页码范围: 1083-1084
• 页数: 2页
• 语种: 英文

摘要

Photoredox catalysis has changed the landscape of modern synthetic organic chemistry by prompting a dramatic increase in research activity into reactions that proceed through free radical intermediates [1].Instrumental in this shift in interest from two-electron to single-electron processes was the widespread appreciation of the synthetic utility of photoactive precious metal complexes,including Ru(bpy)32+ (bpy=2,2'-bipyridine) and Ir(ppy)3 (ppy=2-phenylpyridine).