Furfural Reduction via Hydrogen Transfer from Supercritical Methanol

• 来源期刊: 高等学校化学研究（英文版）
• 年，卷（期）: 2019,（3）
• 页码范围: 498-503
• 页数: 6页
• 语种: 英文
• DOI: 10.1007/s40242-019-8319-y

摘要

Furfural derived from biomass hemicelluloses is an important intermediate for biofuels and chemicals.In order to further upgrade,furfural is usually reduced into 2-methyl furan that is more stable and useful.In this work,furfural was reduced by CuZnA1,CuMgA1,Cu2Cr2O5,CuNiA1 as catalysts in a supercritical methanol without external H2 source.The best yield of 2-methyl furan was achieved anong the H2 free furfural process reported as high as 74％.And the catalytic behaviors were discussed under different catalysts and temperatures conditions.