Near 100% selectivity for visible-light-driven CO2 reduction to CH4 on a dual-metal site photocatalyst
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摘要:
Photocatalytic CO2 reduction is a potential method to convert solar energy to chemicals,which has aroused extensive attention during the past decades.However,the process of CO2 reduction is a multiple proton coupled electron transfer reaction,which leads to a wide variety of final products,such as CO,CH4.Moreover,H+ reduction is a competitive reaction and further lowers the selectivity of CO2 reduction [1-3].