Reductive Amination of Carbonyl Compounds with Ammonia and Hydrogenation of Nitriles to Primary Amines with Heterogeneous Cobalt Catalysts

• 来源期刊: 高等学校化学研究（英文版）
• 年，卷（期）: 2019,（3）
• 页码范围: 457-462
• 页数: 6页
• 语种: 英文
• DOI: 10.1007/s40242-019-8390-4

摘要

Reductive amination of aldehydes/ketones with aqueous NH3 and hydrogenation of nitriles to primary amines with Co catalysts were reported.Co@NC-700 exhibited remarkable activity and high selectivity for the reductive amination of aldehydes/ketones with aqueous NH3 and the hydrogenation of nitriles to primary amines.Several primary amines can be obtained with good to excellent yields via the reductive amination of aldehydes/ketones and the hydrogenation of nitriles.The nitrogen-doped carbon(C)-supported Co@NC-700 metal catalyst was prepared via the pyrolysis ofbioMOF Co/adenine in activated C.Co@NC-700 can be reused five times without evident loss of activity.